M-45 Mancozeb 75%WP Fungicides

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NOMENCLATURE
Common name mancozeb (BSI, E-ISO); mancozèbe ((m) F-ISO); manzeb (JMAF)
IUPAC name manganese ethylenebis(dithiocarbamate) (polymeric) complex with zinc salt
Chemical Abstracts name [[1,2-ethanediylbis[carbamodithioato]](2-)]manganese mixture with [[1,2-ethanediylbis[carbamodithioato]](2-)]zinc
CAS RN [8018-01-7] (formerly [8065-67-6]); [8018-01-7] is also applied to other mixed manganese and zinc ethylenebis(dithiocarbamate) complexes

Physical Chemistry:-
Composition The ISO definition is ‘a complex of zinc and maneb containing 20% of manganese and 2.55% of zinc, the salt present being stated (for instance mancozeb chloride)’. Form Greyish-yellow powder. M.p. Decomposes at 192-204 ºC V.p. Negligible at 20 ºC S.g./density 1.92 Solubility In water 6.2 ppm (pH 7.5, 25 °C). Insoluble in most organic solvents; dissolves in solutions of powerful chelating agents but cannot be recovered from them. Stability Stable under normal, dry storage conditions. Slowly decomposed by heat and moisture. On hydrolysis (25 ºC), DT50 20 d (pH 5), 17 h (pH 7), 34 h (pH 9). Mancozeb a.i. is unstable and the tech. not isolated; the formulated product is produced in continuous process. F.p. 137.8 ºC (Tag open cup)

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